Characteristics and Applications of Polymers - Factors That Influence Melting and Glass Transition Temperatures

6 important questions on Characteristics and Applications of Polymers - Factors That Influence Melting and Glass Transition Temperatures

What influences the melting temperature of a polymer?

Molecular chemistry and structure have affect on the ability to rearrange, and therefor the melting temperature.
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How does chain stiffness effect the melting temperature?

The stiffer the chain the higher Tm.
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Which factors, that influence chain stiffness, increase Tm?

- Double bonds or aromatic groups
- Bulky or large side groups
- Polar groups
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How does molecular weight influence melting temperature?

Increasing the average molecular weight of a polymer will raise the melting temperature.
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How does the degree of branching affects the melting temperature of a polymer?

When there are more side branches the crystal regions will have more defects. This will lower the melting temperature.
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How does the degree of branching influence the Tg?

A small amount of branching lowers the Tg, but a high density of branches raises the Tg.
Crosslinking highly restricts molecular motion and these polymers will not experience a glass transition.
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